Q. \[ 2\mathrm{H}_2\mathrm{O}_2 \rightarrow 2\mathrm{H}_2\mathrm{O} + \mathrm{O}_2 \]

Answer

Balanced reaction: \[2\mathrm{H}_2\mathrm{O}_2 = 2\mathrm{H}_2\mathrm{O} + \mathrm{O}_2\]. Check atoms. Hydrogen: left \(2\times 2 = 4\), right \(2\times 2 = 4\). Oxygen: left \(2\times 2 = 4\), right \(2\times 1 + 2 = 4\). Hence the equation is balanced as written: \[2\mathrm{H}_2\mathrm{O}_2 = 2\mathrm{H}_2\mathrm{O} + \mathrm{O}_2\].

Detailed Explanation

Goal. Balance the chemical equation for the decomposition of hydrogen peroxide given as \( \mathrm{H}_2\mathrm{O}_2 \) forming water and oxygen. We will find integer coefficients \(a,b,c\) for the general form \( a\,\mathrm{H}_2\mathrm{O}_2 = b\,\mathrm{H}_2\mathrm{O} + c\,\mathrm{O}_2 \).

Step 1. Write atom-balance equations. Count hydrogen and oxygen atoms on each side and write algebraic equations for those counts.

Hydrogen balance. Each molecule of \( \mathrm{H}_2\mathrm{O}_2 \) contains 2 hydrogen atoms, and each molecule of \( \mathrm{H}_2\mathrm{O} \) contains 2 hydrogen atoms. Therefore the hydrogen equation is \( 2a = 2b \).

Oxygen balance. Each molecule of \( \mathrm{H}_2\mathrm{O}_2 \) contains 2 oxygen atoms. Each molecule of \( \mathrm{H}_2\mathrm{O} \) contains 1 oxygen atom, and each molecule of \( \mathrm{O}_2 \) contains 2 oxygen atoms. Therefore the oxygen equation is \( 2a = b + 2c \).

Step 2. Solve the system. From the hydrogen equation \( 2a = 2b \) we get \( a = b \). Substitute \( b = a \) into the oxygen equation \( 2a = b + 2c \) to obtain \( 2a = a + 2c \). Rearranging gives \( a = 2c \). To get the smallest positive integer coefficients, choose \( c = 1 \). Then \( a = 2 \) and \( b = a = 2 \).

Step 3. Write the balanced equation. With coefficients \( a=2 \), \( b=2 \), \( c=1 \) the balanced equation is

\[ 2\,\mathrm{H}_2\mathrm{O}_2 = 2\,\mathrm{H}_2\mathrm{O} + \mathrm{O}_2 \]

Step 4. Verify by counting atoms. Left side: hydrogen \(2\times 2 = 4\) atoms, oxygen \(2\times 2 = 4\) atoms. Right side: hydrogen \(2\times 2 = 4\) atoms from \(2\,\mathrm{H}_2\mathrm{O}\), oxygen \(1\times 2 = 2\) atoms from \(2\,\mathrm{H}_2\mathrm{O}\) plus \(2\) atoms from \(\mathrm{O}_2\), total oxygen \(2 + 2 = 4\). Both elements balance, so the equation is correctly balanced.

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Chemistry FAQs

What reaction is this?

This is the decomposition of hydrogen peroxide: \(2\mathrm{H}_2\mathrm{O}_2 \rightarrow 2\mathrm{H}_2\mathrm{O} + \mathrm{O}_2\). It shows hydrogen peroxide breaking down into water and oxygen gas.

Is the equation balanced?

Yes. Left: 4 H and 4 O. Right: \(2\mathrm{H}_2\mathrm{O}\) gives 4 H and 2 O, plus \(\mathrm{O}_2\) adds 2 O, totaling 4 O. Atoms and charge are conserved.

What type of reaction is this?

It is decomposition reaction and redox reaction. Oxygen in \(\mathrm{H}_2\mathrm{O}_2\) undergoes simultaneous oxidation and reduction (disproportionation).

What is the stoichiometric ratio of H2O2 to O2?

From \(2\mathrm{H}_2\mathrm{O}_2 \rightarrow 2\mathrm{H}_2\mathrm{O} + \mathrm{O}_2\), 2 moles H2O2 produce 1 mole O2. Ratio H2O2 : O2 = 2 : 1.

How many moles of O2 from x grams of H2O2?

Compute moles H2O2 = mass / 34.014 g·mol⁻¹. Moles O2 = 0.5 × moles H2O2. So moles O2 = 0.5 × (mass / 34.014).

Does this reaction need catalyst?

Decomposition is slow alone. Catalysts like catalase (enzymatic) or transition metal ions speed it up. Catalysts lower activation energy but are not consumed.

Is the reaction exothermic or endothermic?

Decomposition of hydrogen peroxide is exothermic overall. It releases heat, which can accelerate the reaction and cause rapid decomposition if not controlled.

How do oxidation states change for oxygen?

In \(\mathrm{H}_2\mathrm{O}_2\), O has oxidation state -1. In \(\mathrm{H}_2\mathrm{O}\), O is -2. In \(\mathrm{O}_2\), O is 0. One oxygen is reduced, the other is oxidized (disproportionation).
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