Q. \( \mathrm{BaCl_2} \) lewis structure

Answer

\( \mathrm{BaCl_2} \) is made of ionic ions: \( \mathrm{Ba^{2+}} \) and \( \mathrm{Cl^-} \).

Steps (quick explanation):

\( \mathrm{Ba} \) has 2 valence electrons, and each \( \mathrm{Cl} \) needs 1 more electron to complete an octet. Barium transfers 2 electrons total to two chlorine atoms.

Lewis structure (ionic form):

\( \mathrm{Ba^{2+}} \) (no valence electrons drawn) and two \( \mathrm{Cl^-} \) ions. Each \( \mathrm{Cl^-} \) has 8 valence electrons: 3 lone pairs and 1 extra lone pair, for a total of 4 lone pairs per chlorine.

Final structure:

\( \mathrm{:Cl: \! – \! Ba^{2+} \! – \! :Cl:} \) with each \( \mathrm{Cl} \) having 4 lone pairs and barium having none drawn.

Detailed Explanation

Below is how to draw the Lewis structure for BaCl2 step by step, including the reasoning you would use as a chemistry tutor.

Step 1: Identify the type of compound

BaCl2 is an ionic compound made from barium (Ba) and chlorine (Cl).

Barium is in Group 2, so it tends to form a +2 ion.

Chlorine is in Group 17, so it tends to form a -1 ion.

Step 2: Determine ionic charges

For barium:

\[ \text{Ba} \rightarrow \text{Ba}^{2+} \]

For chlorine:

\[ \text{Cl} \rightarrow \text{Cl}^{-} \]

Since there are two chlorine atoms in BaCl2, you balance charge:

\[ \text{Ba}^{2+} + 2(\text{Cl}^{-}) \]

So the compound is represented as:

\[ \text{BaCl}_2 \equiv \text{Ba}^{2+} + 2\text{Cl}^{-} \]

Step 3: Use valence electrons of each ion to place dots

Chlorine has 7 valence electrons as a neutral atom. When it becomes \(\text{Cl}^-\), it gains one electron to complete its octet.

So each \(\text{Cl}^-\) has:

\[ 8 \text{ valence electrons} \]

That means each chloride ion has an octet, typically shown as 4 lone pairs (8 electrons) around the Cl.

Step 4: Determine what to draw for Ba

Barium forms \(\text{Ba}^{2+}\), meaning it has lost its valence electrons in the ionic picture.

Therefore, Ba is shown as:

\[ \text{Ba}^{2+} \]

and it does not have lone pairs drawn on it (because it is a cation with a stable electron configuration, not an atom keeping bonding electrons as dots).

Step 5: Write the Lewis structure (ionic Lewis structure)

The Lewis structure for BaCl2 is typically drawn as \(\text{Ba}^{2+}\) with two \(\text{Cl}^-\) ions, each having 4 lone pairs.

Final Lewis structure (text description)

\(\text{Ba}^{2+}\) sits in the center, and two \(\text{Cl}^-\) are placed around it.

Each \(\text{Cl}^-\) has four lone pairs.

Final structure in symbolic Lewis form

\[ \text{Ba}^{2+}\ \ \ \ \ :\text{Cl}:\ \ \ \ \ \ :\text{Cl}: \]

Now specify the lone pairs on each chlorine as 4 pairs total:

Each \(\text{Cl}^-\) has:

  • \(4\) lone pairs shown as dots around Cl.

  • The ion charge marked as \( – \).

Important note about how lone pairs are usually pictured

On a diagram, each \(\text{Cl}\) would be surrounded by 8 dots (4 lone pairs), and the overall ions are shown with charges:

  • \(\text{Ba}^{2+}\)

  • \(\text{Cl}^{-}\) with 4 lone pairs on each chlorine

Answer (Lewis structure)

BaCl2 Lewis structure: \(\text{Ba}^{2+}\) with two \(\text{Cl}^{-}\) ions. Each \(\text{Cl}^{-}\) has 4 lone pairs (8 valence electrons) and is typically shown with dots around the Cl.

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General Chemistry FAQs

What is the total valence electron count for \( \text{BaCl}_2 \)?

\( \text{Ba} \) is in group 2 \(\rightarrow 2\) valence electrons, and \(2\) Cl atoms each contribute \(7\). Total \(=2+2(7)=16\) valence electrons.

What oxidation states should be used to build the \( \text{BaCl}_2 \) Lewis structure?

\( \text{Ba} \) forms \( \text{Ba}^{2+} \) and each \( \text{Cl} \) forms \( \text{Cl}^- \). So overall is \( \text{Ba}^{2+}( \text{Cl}^-)_{2} \).

How many lone pairs does each chlorine have in the Lewis structure?

In \( \text{Cl}^- \), chlorine has a filled octet: \(6\) nonbonding electrons \(=3\) lone pairs. So each Cl has \(3\) lone pairs.

Does \( \text{BaCl}_2 \) have bonds drawn between Ba and Cl in a Lewis structure?

Typically drawn as ionic: square brackets \( \)around \( \text{Cl}^- \) with \(3\) lone pairs each, while \( \text{Ba}^{2+} \) has no lone pairs.

What is the formal charge on each atom in the Lewis structure model?

For \( \text{Ba}^{2+} \), formal charge \(=+2\). For each \( \text{Cl}^- \), formal charge \(=-1\). Sum \(+2+(-1)+(-1)=0\).

Can \( \text{BaCl}_2 \) be represented as discrete molecules with covalent bonding?

\( \text{BaCl}_2 \) is usually treated as an ionic compound (metal + halogen). A covalent-molecule Lewis structure is not the standard approach for typical classes.

What is a common final Lewis structure depiction for \( \text{BaCl}_2 \)?

\( \text{Ba}^{2+} \) surrounded by two \( \text{Cl}^- \) ions, each \( \text{Cl}^- \) showing \(3\) lone pairs (16 total valence electrons).
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