Q. \( \mathrm{C_2H_6} \) shape.

Answer

\( \mathrm{C_2H_6} \) is ethane. Its molecular shape is tetrahedral around each carbon, giving an overall staggered conformation in the lowest-energy arrangement.

Final: Staggered conformation; each carbon has tetrahedral geometry.

Detailed Explanation

Goal: Determine the molecular “shape” (geometry) of the substance with formula \( \mathrm{C_2H_6} \), which is ethane.

Step 1: Identify the central atom(s).

In ethane, \( \mathrm{C_2H_6} \), the carbon atoms are connected to each other. Each carbon can be treated as a central atom when considering its local geometry.

Step 2: Count valence electron domains around one carbon.

Focus on one carbon (say the first carbon). Its bonding pattern is:

  • It is bonded to the other carbon by a single bond.
  • It is bonded to three hydrogen atoms by single bonds.

So, around the carbon, there are four regions of electron density (electron domains):

  • 1 bond to carbon
  • 3 bonds to hydrogen

Therefore, the arrangement is \( 4 \) electron domains and there are no lone pairs on carbon.

Step 3: Use VSEPR theory to predict the molecular geometry.

With \( 4 \) electron domains and \( 0 \) lone pairs, the electron-domain geometry is tetrahedral, and the molecular shape is also tetrahedral.

For a carbon center:

\[
\mathrm{C}\text{ has }4\text{ sigma bonds} \Rightarrow \text{tetrahedral geometry}
\]

Step 4: Describe the shape for the whole molecule.

Ethane has two tetrahedral carbon centers connected by a single bond. Each carbon is locally tetrahedral, meaning each carbon has bond angles close to the tetrahedral angle.

Step 5: State the key bond angle.

For tetrahedral geometry, the ideal bond angle is:

\[
\theta \approx 109.5^\circ
\]

Final Answer (molecular shape of \( \mathrm{C_2H_6} \)).

\( \mathrm{C_2H_6} \) (ethane) consists of two \( sp^3 \) (tetrahedral) carbon centers; each carbon has a tetrahedral geometry with approximately \( 109.5^\circ \) bond angles.

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General Chemistry FAQs

What is the molecular shape of \( \mathrm{C_2H_6} \)?

\( \mathrm{C_2H_6} \) is ethane. Its shape is tetrahedral around each carbon, with an overall staggered conformer for the lowest-energy form.

What is the geometry around each carbon in \( \mathrm{C_2H_6} \)?

Each carbon has four electron domains (4 bonds, no lone pairs). By VSEPR, the local geometry is tetrahedral.

How many \( \sigma \) bonds and what hybridization are present?

There are 6 \( \sigma \) bonds: \( \mathrm{C-C} \) and 5 \( \mathrm{C-H} \). Each carbon is \( sp^3 \) hybridized.

What torsional conformations exist for ethane, and which is most stable?

Ethane has staggered and eclipsed conformers. The staggered form is most stable (lower energy) due to minimized electron repulsion.

What are the approximate bond angles in \( \mathrm{C_2H_6} \)?

Ideal tetrahedral bond angles are about \( 109.5^\circ \) between \( \mathrm{H-C-H} \) or \( \mathrm{H-C-C} \) directions.

What is the effect of the staggered vs eclipsed arrangement on energy?

Eclipsed conformations have higher energy because bonds overlap more (greater repulsion). Staggered conformations reduce overlap and are lower in energy.
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