Q. Electron configuration fe.

Answer

“Fe” is iron, with atomic number \(26\). Fill orbitals in the order \(1s, 2s, 2p, 3s, 3p, 4s, 3d\) until all \(26\) electrons are placed.

\[
\text{Fe: } 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6
\]

So the electron configuration of iron is

\(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^6\).

Detailed Explanation

We want the electron configuration of iron, \( \mathrm{Fe} \).

Step 1: Identify the atomic number of iron.

\( \mathrm{Fe} \) has atomic number \(26\). That means a neutral iron atom has \(26\) electrons total.

Step 2: Fill orbitals in order of increasing energy (the aufbau principle).

For elements up to iron, we fill orbitals in this standard order:

\[
\mathrm{1s,\ 2s,\ 2p,\ 3s,\ 3p,\ 4s,\ 3d}
\]

Step 3: Write the configuration for each shell and subshell.

\[
\begin{aligned}
\mathrm{1s}^2 &: \ 2 \text{ electrons} \\
\mathrm{2s}^2 &: \ 2 \text{ electrons (total }4\text{)} \\
\mathrm{2p}^6 &: \ 6 \text{ electrons (total }10\text{)} \\
\mathrm{3s}^2 &: \ 2 \text{ electrons (total }12\text{)} \\
\mathrm{3p}^6 &: \ 6 \text{ electrons (total }18\text{)} \\
\mathrm{4s}^2 &: \ 2 \text{ electrons (total }20\text{)} \\
\mathrm{3d}^6 &: \ 6 \text{ electrons (total }26\text{)}
\end{aligned}
\]

Step 4: Combine everything into the full electron configuration.

\[
\mathrm{Fe:}\quad 1s^2\ 2s^2\ 2p^6\ 3s^2\ 3p^6\ 4s^2\ 3d^6
\]

Final answer:

\[
\mathrm{Fe = 1s^2\ 2s^2\ 2p^6\ 3s^2\ 3p^6\ 4s^2\ 3d^6}
\]

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General Chemistry FAQs

What is the ground-state electron configuration of \( \mathrm{Fe} \) (atomic number 26)?

\(\mathrm{Fe}: 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6\). Iron fills \(4s\) before \(3d\), giving \(3d^6\).

How do you write the shorthand (noble-gas) electron configuration for \( \mathrm{Fe} \)?

\(\mathrm{Fe}:[\mathrm{Ar}]\,4s^2\,3d^6\). Start from argon \((18\) electrons\()\) and add \(8\) more: \(4s^2\,3d^6\).

What is the valence electron configuration for \( \mathrm{Fe} \)?

The valence shell includes \(4s\) and \(3d\): \(\mathrm{Fe}:4s^2\,3d^6\). These electrons are most involved in bonding and chemistry.

What are the electron-filled subshell occupations \( (4s \text{ and } 3d) \) for \( \mathrm{Fe} \)?

In the ground state, \(\mathrm{Fe}\) has \(4s^2\) and \(3d^6\). So \(4s\) holds 2 electrons, and \(3d\) holds 6 electrons.

Why does electrons fill \(4s\) before \(3d\) in \( \mathrm{Fe} \)?

The \(4s\) subshell has lower energy than \(3d\) when filling in the neutral atom. This ordering gives \(4s^2\) first, then \(3d^6\) for iron.

What is the electron configuration of \( \mathrm{Fe^{2+}} \) compared to neutral \( \mathrm{Fe} \)?

Neutral: \([\mathrm{Ar}]\,4s^2\,3d^6\). For \( \mathrm{Fe^{2+}} \), remove two \(4s\) electrons: \([\mathrm{Ar}]\,3d^6\). The \(3d\) electrons stay.
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