Q. What is the molecular geometry of \(\mathrm{CO_2}\)?

Answer

CO\(_2\) has the central carbon atom with two double-bonded oxygens. There are 2 electron regions (2 groups), so the electron-domain geometry is linear, the molecular geometry is also linear, and the bond angle is \(180^\circ\).

Final result: Linear molecular geometry, with O–C–O bond angle \(180^\circ\).

Detailed Explanation

\( \textbf{Goal:} \) Determine the molecular geometry of carbon dioxide, \( \text{CO}_2 \).

\( \textbf{Step 1: Identify the Lewis structure and the central atom} \)

\( \text{CO}_2 \) has the structure \( \text{O}=\text{C}=\text{O} \). The central (least electronegative) atom is carbon.

\( \textbf{Step 2: Count electron-domain regions around the central atom} \)

Geometry is determined by the number of electron domains (regions of electron density) around the central atom using VSEPR theory.

In \( \text{O}=\text{C}=\text{O} \), carbon has two bonding pairs:

\( \cdot \) one double bond to the left oxygen

\( \cdot \) one double bond to the right oxygen

Each double bond counts as one electron domain for VSEPR. So the total number of electron domains around carbon is

\[ \text{Number of electron domains} = 2 \]

\( \textbf{Step 3: Determine the electron-domain geometry} \)

For \(2\) electron domains, the electron-domain geometry is linear.

\( \textbf{Step 4: Check for lone pairs on the central atom} \)

Carbon in \( \text{CO}_2 \) has no lone pairs in the Lewis structure. Therefore, there are no extra electron domains that would bend the molecule.

\( \textbf{Step 5: Name the molecular geometry} \)

With \(2\) electron domains and \(0\) lone pairs on the central atom, the molecular geometry is also linear.

\( \textbf{Final Answer:} \) The molecular geometry of \( \text{CO}_2 \) is \(\textbf{linear}\), with an ideal bond angle of \(180^\circ\).

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General Chemistry FAQs

What is the molecular geometry of \( \mathrm{CO_2} \)?

\( \mathrm{CO_2} \) has a linear molecular geometry, with the atoms arranged in a straight line.

What is the bond angle in linear \( \mathrm{CO_2} \)?

The bond angle is \(180^\circ\) (O=C=O).

How many electron domains and what is the resulting geometry?

\( \mathrm{CO_2} \) has 2 electron domains around the central carbon, giving a linear electron-domain geometry.

What is the hybridization of carbon in \( \mathrm{CO_2} \)?

Carbon is \(sp\)-hybridized, which supports a linear arrangement of the two double bonds.

Does \( \mathrm{CO_2} \) have a bent molecular shape?

No. Because carbon has no lone pairs on the central atom, steric effects are minimal and the molecule remains linear.

Is \( \mathrm{CO_2} \) polar or nonpolar despite linear geometry?

\( \mathrm{CO_2} \) is nonpolar overall because the equal and opposite bond dipoles cancel in the linear structure.

What is the Lewis structure description for \( \mathrm{CO_2} \)?

The Lewis structure is O=\( \mathrm{C} \)=O, with two double bonds between carbon and each oxygen.
CO2 is linear in shape.
Bond angles are 180°.
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