Q. Fe orbital diagram.

Answer

Fe (iron), atomic number \(26\)

Electron configuration

\( \mathrm{Fe}: 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6 \)

\(3d\) orbital diagram (Fe)

\[
\mathrm{3d:}\;\;\;
\begin{array}{cc}
\Box & \\
\Box & \\
\Box & \\
\Box & \\
\Box &
\\
\end{array}
\]

Hund’s rule filling for \(3d^6\)

\( \uparrow \;\uparrow \;\uparrow \;\uparrow \;\uparrow \;\downarrow \)

Final (orbital diagram result)

\(3d^6\) means five unpaired electrons in the five \(d\) orbitals, and the sixth electron paired in one orbital: \(\;\uparrow \downarrow\), and the other four are \(\uparrow\).

Detailed Explanation

Step 1: Identify the atomic number

Iron, \( \mathrm{Fe} \), has atomic number \(26\). That means it has \(26\) electrons.


Step 2: Write the electron configuration in order of filling (Aufbau principle)

Electrons fill orbitals in increasing energy order:
\(1s, 2s, 2p, 3s, 3p, 4s, 3d\).

For iron:

\[
\mathrm{Fe}: \ 1s^2\ 2s^2\ 2p^6\ 3s^2\ 3p^6\ 4s^2\ 3d^6
\]


Step 3: Convert the configuration into subshell box (orbital) diagrams

Each orbital box holds at most \(2\) electrons with opposite spins.

Here are the filled orbitals:

\(1s\) (filled with 2 electrons)

\[
1s:\ \uparrow\downarrow
\]

\(2s\) (filled with 2 electrons)

\[
2s:\ \uparrow\downarrow
\]

\(2p\) (3 orbitals, total 6 electrons → all filled)

\[
2p:\
\begin{matrix}
\uparrow\downarrow & \uparrow\downarrow & \uparrow\downarrow
\end{matrix}
\]

\(3s\) (filled with 2 electrons)

\[
3s:\ \uparrow\downarrow
\]

\(3p\) (3 orbitals, total 6 electrons → all filled)

\[
3p:\
\begin{matrix}
\uparrow\downarrow & \uparrow\downarrow & \uparrow\downarrow
\end{matrix}
\]

\(4s\) (filled with 2 electrons)

\[
4s:\ \uparrow\downarrow
\]

\(3d\) (5 orbitals, total 6 electrons)

First place one electron in each \(3d\) orbital (Hund’s rule), then add the 6th electron to complete pairing in the next available orbital.

\(3d\) has 5 boxes:

\[
3d:\
\begin{matrix}
\uparrow\downarrow & \uparrow & \uparrow & \uparrow & \uparrow
\end{matrix}
\]


Step 4: Final orbital occupancy summary (most important part is \(4s\) and \(3d\))

The key result for iron is:

  • \(4s^2\)
  • \(3d^6\)

Full orbital filling can be summarized as:

\[
\mathrm{Fe}:\ 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6
\]

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General Chemistry FAQs

What is the ground-state electron configuration for iron, Fe, and how many electrons are in each shell?

Fe has \(26\) electrons. Ground-state configuration: \(1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6\). Quartets: \(n=1:2\), \(n=2:8\), \(n=3:14\), \(n=4:2\) (plus \(3d^6\)).

How do you write the Fe orbital diagram for the \(4s\) and \(3d\) subshells?

For \(4s\): \(4s^2\) means paired electrons in one orbital. For \(3d\): \(3d^6\) means five \(3d\) orbitals follow Hund’s rule, with the first five singly occupied, leaving one paired. Total in \(3d\) is \(6\).

What does Hund’s rule predict specifically for \(3d^6\) in Fe?

Hund’s rule: maximize unpaired electrons before pairing. For \(3d^6\), fill \(5\) orbitals singly (\(5\) unpaired), then place the \(6\)th electron by pairing in one orbital. So Fe has \(4\) unpaired electrons (overall in \(3d\) only).

Why does iron use \(4s^2\,3d^6\) rather than \(4s^1\,3d^7\)?

The energy ordering in neutral Fe favors filling \(4s\) before \(3d\) for the ground state. Thus the Aufbau filling gives \(4s^2\) and then \(3d^6\). \(4s^1\,3d^7\) would be higher in energy, not the ground state.

What changes in the orbital diagram for \(\mathrm{Fe^{2+}}\)?

Remove electrons from the highest-energy subshell first: usually \(4s\) electrons. Starting from Fe: \(4s^2\,3d^6\). For \(\mathrm{Fe^{2+}}\): remove two \(4s\) electrons to get \(4s^0\,3d^6\). The \(3d\) orbital occupancy stays like \(3d^6\) with \(4\) unpaired electrons.

What is the orbital diagram for \(\mathrm{Fe^{3+}}\), and how many unpaired electrons are there?

From Fe: \(4s^2\,3d^6\). For \(\mathrm{Fe^{3+}}\), remove three electrons: \(4s^2\) first and then one from \(3d\). Result: \(4s^0\,3d^5\). For \(3d^5\) (half-filled), all five are singly occupied, giving \(5\) unpaired electrons.

How to count the number of unpaired electrons in Fe’s ground state?

In Fe: \(4s^2\) is paired, contributes \(0\) unpaired. The \(3d^6\) has one extra electron paired after five are singly filled. Unpaired in \(3d^6\): \(4\). So total unpaired electrons for neutral Fe is \(4\).
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