Q. Fe orbital diagram.
Answer
Fe (iron), atomic number \(26\)
Electron configuration
\( \mathrm{Fe}: 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6 \)
\(3d\) orbital diagram (Fe)
\[
\mathrm{3d:}\;\;\;
\begin{array}{cc}
\Box & \\
\Box & \\
\Box & \\
\Box & \\
\Box &
\\
\end{array}
\]
Hund’s rule filling for \(3d^6\)
\( \uparrow \;\uparrow \;\uparrow \;\uparrow \;\uparrow \;\downarrow \)
Final (orbital diagram result)
\(3d^6\) means five unpaired electrons in the five \(d\) orbitals, and the sixth electron paired in one orbital: \(\;\uparrow \downarrow\), and the other four are \(\uparrow\).
Detailed Explanation
Step 1: Identify the atomic number
Iron, \( \mathrm{Fe} \), has atomic number \(26\). That means it has \(26\) electrons.
Step 2: Write the electron configuration in order of filling (Aufbau principle)
Electrons fill orbitals in increasing energy order:
\(1s, 2s, 2p, 3s, 3p, 4s, 3d\).
For iron:
\[
\mathrm{Fe}: \ 1s^2\ 2s^2\ 2p^6\ 3s^2\ 3p^6\ 4s^2\ 3d^6
\]
Step 3: Convert the configuration into subshell box (orbital) diagrams
Each orbital box holds at most \(2\) electrons with opposite spins.
Here are the filled orbitals:
\(1s\) (filled with 2 electrons)
\[
1s:\ \uparrow\downarrow
\]
\(2s\) (filled with 2 electrons)
\[
2s:\ \uparrow\downarrow
\]
\(2p\) (3 orbitals, total 6 electrons → all filled)
\[
2p:\
\begin{matrix}
\uparrow\downarrow & \uparrow\downarrow & \uparrow\downarrow
\end{matrix}
\]
\(3s\) (filled with 2 electrons)
\[
3s:\ \uparrow\downarrow
\]
\(3p\) (3 orbitals, total 6 electrons → all filled)
\[
3p:\
\begin{matrix}
\uparrow\downarrow & \uparrow\downarrow & \uparrow\downarrow
\end{matrix}
\]
\(4s\) (filled with 2 electrons)
\[
4s:\ \uparrow\downarrow
\]
\(3d\) (5 orbitals, total 6 electrons)
First place one electron in each \(3d\) orbital (Hund’s rule), then add the 6th electron to complete pairing in the next available orbital.
\(3d\) has 5 boxes:
\[
3d:\
\begin{matrix}
\uparrow\downarrow & \uparrow & \uparrow & \uparrow & \uparrow
\end{matrix}
\]
Step 4: Final orbital occupancy summary (most important part is \(4s\) and \(3d\))
The key result for iron is:
- \(4s^2\)
- \(3d^6\)
Full orbital filling can be summarized as:
\[
\mathrm{Fe}:\ 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,4s^2\,3d^6
\]
General Chemistry FAQs
What is the ground-state electron configuration for iron, Fe, and how many electrons are in each shell?
How do you write the Fe orbital diagram for the \(4s\) and \(3d\) subshells?
What does Hund’s rule predict specifically for \(3d^6\) in Fe?
Why does iron use \(4s^2\,3d^6\) rather than \(4s^1\,3d^7\)?
What changes in the orbital diagram for \(\mathrm{Fe^{2+}}\)?
What is the orbital diagram for \(\mathrm{Fe^{3+}}\), and how many unpaired electrons are there?
How to count the number of unpaired electrons in Fe’s ground state?
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