Q. Orbital diagram for Mg.

Answer

Magnesium, \( \text{Mg} \), has atomic number \(12\). So it has \(12\) electrons.

Electron configuration filling order:

\[
\text{1s}^2\ \text{2s}^2\ \text{2p}^6\ \text{3s}^2
\]

Orbital (box) diagram:
1s: \(\uparrow\downarrow\)
2s: \(\uparrow\downarrow\)
2p: \(\uparrow\downarrow\ \ \uparrow\downarrow\ \ \uparrow\downarrow\)
3s: \(\uparrow\downarrow\)

Final orbital diagram corresponds to the filling: \( \text{1s}^2\,2\text{s}^2\,2\text{p}^6\,3\text{s}^2 \).

Detailed Explanation

An orbital diagram for magnesium (Mg) shows how its electrons fill orbitals according to the aufbau principle, the Pauli exclusion principle, and Hund’s rule.

First, identify the atomic number of magnesium.

\( \text{Mg} \) has atomic number \(12\), so a neutral Mg atom has \(12\) electrons.

Write the electron configuration by filling subshells in order of increasing energy.

The electrons fill in this order (lowest energy first): \(1s\), \(2s\), \(2p\), \(3s\).

Count and place electrons into each subshell.

  • \(1s\): holds up to 2 electrons, so Mg gets \(2\).
  • \(2s\): holds up to 2 electrons, so Mg gets \(2\).
  • \(2p\): holds up to 6 electrons, so Mg gets \(6\).
  • \(3s\): holds up to 2 electrons, so Mg gets the remaining \(2\).

This gives the electron configuration:

\[
\text{Mg: } 1s^2\, 2s^2\, 2p^6\, 3s^2
\]

Now construct the orbital diagram by drawing each subshell as boxes and placing electrons as arrows (one arrow in each box can represent one electron; direction is used to show opposite spins).

Orbital diagram for Mg (showing individual orbitals):

\[
\begin{array}{c}
1s: \quad \uparrow\downarrow \\
\\
2s: \quad \uparrow\downarrow \\
\\
2p: \quad \uparrow\downarrow \quad \uparrow\downarrow \quad \uparrow\downarrow \\
\\
3s: \quad \uparrow\downarrow
\end{array}
\]

Alternatively, written in a single compact orbital-box style (one set of three boxes for \(2p\)):

\[
\begin{array}{c}
1s:\ [\uparrow\downarrow] \\
2s:\ [\uparrow\downarrow] \\
2p:\ [\uparrow\downarrow]\ [\uparrow\downarrow]\ [\uparrow\downarrow] \\
3s:\ [\uparrow\downarrow]
\end{array}
\]

Key check: Count the electrons to ensure it matches \(12\).

\(1s^2\) gives \(2\), \(2s^2\) gives \(2\), \(2p^6\) gives \(6\), and \(3s^2\) gives \(2\).
Total \(2+2+6+2 = 12\).

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General Chemistry FAQs

What is the electron configuration of Mg?

Mg has atomic number \(12\). Its ground-state configuration is \(1s^{2}\,2s^{2}\,2p^{6}\,3s^{2}\).

How do you write the orbital diagram for Mg?

Fill orbitals by increasing energy. Occupancies: \(1s\) has 2 electrons, \(2s\) has 2, \(2p\) has 6 (all filled), and \(3s\) has 2.

Which orbitals are filled and which are empty in Mg’s orbital diagram?

Filled: \(1s\), \(2s\), \(2p\), and \(3s\). Empty: \(3p\) orbitals (all empty in the ground state).

What are the quantum numbers for the occupied orbitals in Mg?

Occupied subshells: \(1s\) \((n=1,\,\ell=0)\), \(2s\) \((n=2,\,\ell=0)\), \(2p\) \((n=2,\,\ell=1)\), \(3s\) \((n=3,\,\ell=0)\).

How can I confirm Hund’s rule does not change anything for Mg?

The \(2p\) subshell has 6 electrons, so all three \(2p\) orbitals are filled with paired electrons. There’s no partially filled subshell left to apply additional distribution changes beyond filling.

Why is there a filled \(2p\) subshell in magnesium’s diagram?

After filling \(1s^{2}2s^{2}\), the next electrons go into \(2p\) sublevel. Mg reaches \(2p^{6}\) so all \(2p\) orbitals end up full.
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